Solution

ID: past-exam-of-the-chemistry-course-of-the-year-3-of-the-natural-sciences-course-of-the-university-of-cambridge/2022/paper-2b/section-a/29/a/solution

Use the axes actually printed: the two hydrogens lie in the plane, is the principal twofold axis, and is perpendicular to that plane. For a Cartesian-displacement group representation, only atoms left at their own sites contribute to the trace; their vector components must also be transformed. In the order , identity fixes six components, the twofold rotation exchanges the hydrogens, the reflection fixes both hydrogens with vector matrix , and the reflection exchanges them. Therefore
The nonzero mirror character of a representation is , not six.

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