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ID: past-exam-of-the-materials-science-course-of-the-university-of-cambridge/2019/paper-1/4/b

For a mixture with phase compositions , its molar Gibbs free energy is the straight-line combination at overall . Minimizing over phase compositions gives equal slopes and equal tangent intercepts: the common-tangent construction expresses equality of both component chemical potentials. The equilibrium curve is the lower convex envelope of the candidate phase curves. Phase fractions follow the lever rule.

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