Solution

ID: past-exam-of-the-mathematics-course-of-the-university-of-cambridge/2005/iii/paper-81/4/ii/d/solution

Without surfactant, capillary pressure drives a surface flow towards a growing bulge. Advection compresses the insoluble surfactant in converging parts of that motion, increasing concentration and lowering surface tension. The resulting gradient supplies a tangential Marangoni stress that opposes the surface motion. This additional resistance slows capillary-driven redistribution of liquid even after the base-tension decrease has already been accounted for.
In the strong-elasticity limit, concentration gradients suppress tangential interface motion. The surface behaves as effectively immobile at leading order. Setting in the velocity formula gives , hence
one-quarter of the clean shear-free mobility . This mobility reduction explains the quarter-rate limit; it slows the unstable capillary mode without removing the long-wave unstable band.

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