Solution

ID: past-exam-of-the-mathematics-course-of-the-university-of-cambridge/2017/ib/paper-1/15b/a/solution

Define the parity operator by . For the usual full-line Hamiltonian operator, or any parity-invariant operator domain and boundary conditions, an even potential gives : the second derivative is unchanged by reflection and . If , then . A nondegenerate energy eigenvalue has a one-dimensional eigenspace, so for some scalar . Since , . Hence
Thus the stationary state has even or odd parity. The symmetry must include the operator domain: an even potential alone would not imply this conclusion with asymmetric boundary conditions.

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