 Solution

Take the dual numbers $A=k[\epsilon ]/({\epsilon }^2)$ over any field $k$, let $B=k$, and let $\alpha$ send $\epsilon$ to zero. Its kernel is the nonzero ideal $(\epsilon )$, but both spectra of rings have exactly one point: every prime ideal contains the nilpotent element $\epsilon$, and the only prime of $A$ is $(\epsilon )$. Consequently the induced map is a homeomorphism for the Zariski topology, although it is not an isomorphism of schemes:More generally, quotienting by a nilpotent ideal gives a nilpotent thickening with unchanged underlying topology. The structure sheaf retains information that the topology alone cannot recover.