Solution

ID: past-exam-of-the-mathematics-course-of-the-university-of-cambridge/2019/ii/paper-1/35d/b/solution

At fixed volume, entropy from heat capacity obeys . The Third law of thermodynamics fixes when the ground state is nondegenerate, so below the transition
Above the transition,
For a transition with no latent heat, entropy is continuous, and comparison with gives the directly testable relation
Thus calorimetric measurements of and verify . More generally, if a measurable latent heat is present, , and the formula becomes

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