Solution

ID: past-exam-of-the-physics-a-course-of-the-university-of-cambridge/2010/paper-2/section-b/b9/c/solution

At coincidence , the triplet state spatial factor vanishes, while the lowest singlet state has finite, uniform pair probability. Consequently a weak short-range repulsion raises the singlet state energy more strongly: antisymmetry suppresses close encounters in the triplet state. In the contact-interaction limit the triplet state contribution is exactly zero, whereas the singlet state shift is positive. A finite-range interaction gives a nonzero but suppressed triplet state shift. This explains a relative energy increase; it does not by itself establish a crossing or justify using unchanged noninteracting wavefunctions for arbitrarily strong repulsion.

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