 Solution

A pure stationary state of a time-independent Hamiltonian operator is $\Psi (\mathbf{r},t)=\psi (\mathbf{r})e^{-iEt/\hslash }$. Its probability density and all expectations of time-independent observables are constant. This does not require zero probability current.

For real scalar potential energy and no vector potential, substitute $i\hslash \dot{\Psi }=-({\hslash }^2/2m){\nabla }^2\Psi +V\Psi$ and its complex conjugate into $\dot{\rho }={\Psi }^{\ast }\dot{\Psi }+{\dot{\Psi }}^{\ast }\Psi$. The potential terms cancel:Thus the probability current is $\mathbf{j}=(\hslash /m)\mathrm{Im}({\Psi }^{\ast }\nabla \Psi )$. In a stationary state $\nabla \cdot \mathbf{j}=0$: flow may circulate without changing the density.

Here only the azimuthal phase contributes an imaginary logarithmic derivative. Since $\nabla \varphi =\hat{\mathbf{\varphi }}/(r\sin \theta )$,There is no radial or polar flow; the azimuthal current is independent of $\varphi$, so its divergence vanishes. The apparent coordinate singularity at $\sin \theta =0$ cancels in the final expression.

The z-component of orbital angular momentum follows from the moment of the mass current:Indeed $A^2(24a_0^5)(4/3)(2\pi )=1$. This agrees with $L_z=-i\hslash {\partial }_{\varphi }$ acting on the wavefunction.