Solution

ID: past-exam-of-the-quantum-condensed-matter-course-of-the-university-of-cambridge/2008/section-a/a4/c/solution

Write for a segment length and for the excluded-area coefficient, so that the interaction term has the correct dimensions. For a coil of planar size and area of order , the two-dimensional Flory approximation is
The first term is the entropic stretching cost and the second counts repulsive monomer contacts. Minimization gives , hence
For of order this becomes . The parameter multiplying in a two-dimensional interaction energy must have dimensions of area; it cannot simultaneously denote an unsquared bond length.

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