 Solution

Write $\Psi =(|\downarrow \uparrow ⟩+|\uparrow \downarrow ⟩)/\sqrt{2}$. Each term has cancelling $z$ components, so $S_z\Psi =0$. In the formula for $S^2$, the first three terms contribute $(3/2-1/2){\hslash }^2\Psi ={\hslash }^2\Psi$. The two ladder products exchange the two terms and contribute another ${\hslash }^2\Psi$. ThereforeThis spin state is symmetric; the accompanying spatial state must be antisymmetric for two electrons. A labelled product $|{\downarrow }_1{\uparrow }_2⟩$ alone is not an eigenstate of spin exchange: its exchanged vector is orthogonal to it. Thus it cannot supply a definite exchange symmetry when multiplied by a fixed symmetric spatial factor.

This does not prohibit opposite spins in different spatial orbitals. For example, with orthonormal orbitals ${\varphi }_a,{\varphi }_b$, the Slater determinantis a valid antisymmetric two-electron state. What fails is treating persistent particle labels as physically distinguishable identities without the required antisymmetrization.