This assumes negligible condensation, approximately constant g, well-mixed composition and efficient convection; a radiative or stably stratified layer need not follow it. For mole fractions xN,xC and molar masses MN,MC, Ra=R/(xNMN+xCMC) and cp=[xNCp,N+xCCp,C]/(xNMN+xCMC). Molecular vibrational excitation can make cp depend on temperature; then Γd=g/cp(T). Nitrogen dominance near terrestrial temperatures gives the familiar order 10Kkm−1.