 Solution

Hydrostatic balance and the ideal gas law give $dp/dz=-pg/(R_{a}T)$, hence approximately $p=p_0{e}^{-z/H}$ with $H=R_{a}T/g$ for weak temperature variation. For well-mixed absorber abundance, ${\rho }_{\mathrm{abs}}\propto p/T$, while pressure broadening gives $k\propto p$. Thus $k{\rho }_{\mathrm{abs}}\propto e^{-2z/H}$ and its integral above height $z$ has the same scale. ThereforeThe factor two depends on both pressure dependence of absorption and constant mixing ratio; it is not the ordinary density scale height.