 Solution

The projective measurement probabilities are $P({\sigma }_j=\pm 1)=\mathrm{Tr}[\rho (I\pm {\sigma }_j)/2]$. Both density operators have zero $z$-component of their Bloch vector, soTheir full ${\sigma }_z$ outcome distributions, not merely their mean values, coincide. Along $x$, however,Thus repeated spin measurement along $x$ distinguishes the preparations statistically. A single negative outcome excludes A, while a single positive outcome is compatible with either; under B the probability of $N$ independent positive outcomes is $2^{-N}$.