Solution

ID: past-exam-of-the-thermal-and-statistical-physics-course-of-the-university-of-cambridge/2021/section-b/5/c/solution

Write for the number of cells; this is fixed even though the particle number fluctuates. Approximate each position integral by the cell sum , evaluating the slowly varying intercell pair potential at cell centres. With the assumed single-occupancy restriction, the fixed- contribution becomes
An occupation configuration with selects an unordered set of occupied cells. There are exactly ways to assign the temporary particle labels to that set. They all have the same interaction energy, cancelling the prefactor .
Summing over all particle numbers is therefore equivalent to summing each cell occupation independently over :
The activity per cell, , is dimensionless. This is a lattice gas, with each cell either empty or occupied.
The exclusion of multiple occupation is an additional physical modeling assumption, explicitly imposed by the question. Making a cell small does not by itself forbid two point particles from entering it; a repulsive core or a dilute-occupancy approximation would be needed to justify that restriction starting from a general continuum pair potential. In the remaining parts it is part of the defined cell model.

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