A pH indicator changes color as its protonation distribution changes. In a simple weak acid/conjugate base model, its two forms have different colors and their ratio depends on pH through the acid dissociation constant. The visible transition spans a range of pH; it is not a direct signal that the sample has reached an equivalence point. An indicator is useful when its transition lies in a steep part of the titration curve, so a modest range of pH corresponds to a small added volume.[ref]
14.7 Acid-Base Titrations. Chemistry 2e, §14.7, Acid-Base Indicators, Figures 14.19–14.21: indicator equilibrium, transition ranges, and selection
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