Thermodynamic volume is the volume occupied by a thermodynamic system, treated as an extensive variable.
The volume per amount of substance, with n measured in moles. For a uniform pure substance, vm=M/ρ, where M is its molar mass and ρ its mass density. The Clapeyron equation pairs a difference of molar volumes with latent heat per mole.
The volume divided by the positive number of particles N. The Van der Waals equation uses this convention for v, whereas specific volume divides by mass and molar volume divides by the amount of substance. With the Avogadro constant NA, the molar volume is vm=NAv.
The volume per unit mass; for a uniform substance it is the reciprocal of mass density. The Clapeyron equation pairs a difference of specific volumes with latent heat per unit mass.
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- Absolute pressure in Boyle's law
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- Permanganate-iron endpoint and blank model
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In thermodynamics, volume refers to the amount of space that a substance (solid, liquid, or gas) occupies. It is a fundamental property of matter and plays a crucial role in understanding various thermodynamic processes and laws. Volume can be measured in different units, depending on the system of measurement used. Common units include cubic meters (m³) in the SI system, liters (L), and milliliters (mL).