For an acid-base titration, a volumetric pipette selects an aliquot whose amount of substance is from a homogeneous sample. The delivered volume depends on the instrument's calibration and drainage convention; the residual liquid of a gravity-draining volumetric pipette is allowed for in that calibration. Its mark is read using the liquid meniscus. A volume calibration alone does not establish that the sampled chemical solution has the intended concentration.[ref]
Calibration of Volumetric Glassware (Buffalo State laboratory handout). Laboratory Experiment 1. Calibration of Volumetric Glassware, pp. 1–2, Calibrating 25 mL pipette: eye-level meniscus, gravity drainage, retained liquid
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