Position matrix elements in a symmetric infinite square well
ID: position-matrix-elements-in-a-symmetric-infinite-square-well
For a well , choose normalized energy eigenstates , . The diagonal position matrix elements vanish by the parity operator. For ,To derive it, set and use . For unequal positive integer indices , the constant part of integrates to zero by orthogonality, whileTaking the difference for and yields the formula after setting . It vanishes for equal parity and gives for this phase convention.
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