Second virial coefficient of a bounded cubic repulsion

ID: second-virial-coefficient-of-a-bounded-cubic-repulsion

For a classical dilute gas with pair potential for and zero otherwise, put . Substitution in the Mayer f-function formula gives
It is positive for finite positive temperature, tends to as in the classical model, and behaves as at high temperature. The low-temperature mathematical limit need not remain in the dilute classical regime for a real molecular gas.

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