Thomas M. McDonald investigated cooperative carbon dioxide uptake in diamine-appended metal–organic frameworks. Insertion into metal–amine bonds forms ammonium-carbamate chains, connecting a molecular reaction with the sharp step observed in an adsorption isotherm.[ref]
Cooperative insertion of CO2 in diamine-appended metal-organic frameworks by Thomas M. McDonald and others. 2015, structural/spectroscopic evidence for chain formation and stepped adsorption
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