A carbamate contains the unit . The nitrogen lone pair conjugates with the carbonyl; cyclic carbamates include 2-Oxazolidinone.
A chain arrangement implicated in cooperative carbon-dioxide capture in appropriate diamine-appended metal–organic frameworks. Framework spacing and proton transfer determine the actual adsorption mechanism.[ref]
2-Oxazolidinone is the five-membered cyclic carbamate with ring path . Electrophilic activation of its carbonyl oxygen can generate an imidoyl-type electrophile.

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