 Three-level forbidden-line density diagnostic

In a three-level ion, statistical equilibrium must include collisional coupling between both upper levels as well as excitations from the ground. The upper populations solve a two-by-two linear system when expressed relative to the ground population. Their line ratio is a rational function of electron density, interpolating between a collisionally excited low-density limit and a collisional Boltzmann limit. Closely spaced upper energies reduce temperature sensitivity, but neglecting upper-level collisional mixing can bias the inferred density.