 Uniqueness for a harmonic transmission problem

Let a bounded connected body consist of two regions with positive constant thermal conductivities $k_1,k_2$. A temperature is harmonic in each region, continuous across their interface, has continuous normal heat flux there, and has prescribed outer Dirichlet boundary conditions. There is at most one sufficiently regular solution.

For the difference $w$ of two solutions, apply Green's first identity in each region and multiply by its thermal conductivity. The interface outward normals are opposite, so continuity of $w$ and $k{\partial }_{n}w$ cancels their boundary terms. The outer term vanishes because $w=0$. Hence the displayed sum of nonnegative Dirichlet energies is zero. The gradient vanishes in both regions; continuity and the outer data then force $w=0$. The proof also applies to finitely many connected subregions, provided the union is connected and the same transmission conditions hold.