 Water calorimetry

Water calorimetry measures an energy transfer using the thermal response of water. In radiation metrology, it determines absorbed dose to water from a small measured temperature rise. The ideal conversion follows from $Q=m{c}_w\Delta T$ and $D=Q/m$:where $c_w$ is water's specific heat capacity. The sample mass cancels because dose is energy per unit mass.^[ref]

For an original scale estimate, take $c_w=4180\mathrm{J}\mathrm{k}{\mathrm{g}}^{-1}{\mathrm{K}}^{-1}$ as an illustrative near-room-temperature value. An absorbed dose of $1\mathrm{Gy}=1\mathrm{J}\mathrm{k}{\mathrm{g}}^{-1}$ would then give only $1/4180\mathrm{K}$, about $0.239\mathrm{mK}$. Detecting such a small change requires careful thermometry and separation from background thermal drift.

The physical conversion also has chemical assumptions. Heat defect describes the fraction of absorbed energy that does not appear as heat because of radiation-induced chemical change. Thermal conduction, convection and sensor effects are additional measurement questions, rather than alternate names for that chemical correction. This makes water calorimetry an example of an apparently direct energy measurement whose interpretation still needs a well-defined model.