Superconducting isotope effect 2026-10-18
The superconducting isotope effect is the dependence of the superconducting transition temperature on isotopic mass at fixed chemical composition. Its discovery in 1950 was a crucial clue that phonons participate in conventional superconductivity.[ref]
Electron-Phonon Interactions and Superconductivity by John Bardeen. p.55, isotope-effect discovery and its significance for the electron-phonon mechanism
The model prediction can be derived from two assumptions. For harmonic motion with a fixed restoring-force constant , a phonon frequency scales as . If the BCS dimensionless coupling is independent of , the weak coupling result then gives and . Changes in the effective interaction can change this exponent; it is not a universal law for every material exhibiting superconductivity. For a stipulated mass ratio , the ideal model predicts . This is an original scaling example, not a pair of measured transition temperatures.