Bound-state thresholds of a spherical square well ($V_{s,n}={\pi }^2{\hslash }^2(n+1/2{)}^2/(2\mu a^2)$)

For a spherical square well of radius $a$, depth $V_0$ and reduced mass $\mu$, the regular zero-orbital angular momentum solution has reduced radial wavefunction $U=A\sin kr$ inside and $U=B{e}^{-qr}$ outside. Wavefunction matching at a finite potential step gives $k\cot (ka)=-q$, where $k^2=2\mu (V_0+E)/{\hslash }^2$ and $q^2=-2\mu E/{\hslash }^2$. The $n$th radial branch first reaches $E=0$ at $ka=(n+1/2)\pi$, for $n=0,1,\dots$. A normalizable negative-energy state on that branch requires $V_0>V_{s,n}$. Thus exactly one such state exists for $V_{s,0}<V_0\le V_{s,1}$; the new zero-energy $s$-wave solution at the upper equality is not normalizable.

For the first $\ell =1$ branch, the zero-energy exterior solution has $U\propto r^{-1}$. The regular interior solution is $U\propto r{j}_1(kr)$, where $j_1$ is a Spherical Bessel function. Matching logarithmic derivatives gives $1+z{j}_1^{\prime }(z)/j_1(z)=-1$, or $j_0(z)=0$, with $z=a\sqrt{2\mu V_0}/\hslash$. Its first threshold is $z=\pi$, so $V_{p,0}={\pi }^2{\hslash }^2/(2\mu a^2)$. Higher values of orbital angular momentum increase the positive centrifugal potential, so none can bind below this first $p$-wave threshold. Spin-dependent nuclear forces are absent from this central-well model.