The approximate partition function obtained by decoupling each Ising bond has this free energy. The quadratic constant compensates double counting. Its stationary condition is the self-consistency equation; away from stationarity parametrizes the assumed effective field and need not equal that distribution's mean Ising spin. It agrees at stationary points with the Bragg-Williams free energy of the Ising model, although their off-equilibrium expansions differ.
Use inverse temperature , reserving without a subscript for the critical exponent. Write ; each undirected bond occurs once, so the number of bonds is . In the mean-field theory of the Ising model, write each Ising spin as and neglect the product of fluctuations:
The resulting independent-spin statistical Hamiltonian is
The constant corrects the double counting of interaction energy. The Ising spin sums now factorize and can all be evaluated:
This is the approximate partition function at an assumed mean field; equilibrium fixes self-consistently. The corresponding Ising auxiliary mean-field free energy is
Its equilibrium value gives the mean-field Helmholtz free energy in the imposed field. Away from a stationary point its parameter is an assumed field variable, not necessarily the actual mean Ising spin of that independent-spin distribution.
For the full small- expansion at fixed , set and . Differentiating gives successive derivatives , , , and at . Therefore
At zero field, spin inversion symmetry eliminates odd powers and this simplifies to
The quadratic coefficient changes sign and the quartic coefficient is positive at
Thus the zero-field mean-field prediction is a continuous, continuous phase transition: the stable zero spin magnetization develops two symmetry-related nonzero minima continuously below .
Both requested routes give the same mean-field self-consistency equation. First, the one-spin expectation in the effective field is
Second, differentiating the Ising auxiliary mean-field free energy gives
whose stationary condition is precisely that mean-field self-consistency equation. Choose its stable, lowest-free-energy branch rather than every algebraic solution.
An equally useful mean-field approximation parametrizes the trial distribution by its actual mean Ising spin. Its probabilities are , giving the Bragg-Williams free energy of the Ising model
This energy-minus-entropy function has expansion
Its stationary equation is , again equivalent to the mean-field self-consistency equation. The two functions differ away from equilibrium, but agree on stationary branches: for and , the entropy bracket equals . Their small- coefficients therefore need not agree at arbitrary temperature; at they have the same leading critical quartic coefficient . This distinction prevents confusing the auxiliary-field expansion with the physical-magnetization variational expansion.
For the order-parameter critical exponent, expand the equation of state at :
On a nonzero stable branch,
Hence . The spontaneous magnetization is understood by selecting a branch with an infinitesimal field after the thermodynamic limit; a finite symmetric sample has zero exact zero-field mean Ising spin.
For the magnetic susceptibility per site, define with in energy units. Implicit differentiation gives
Above , and . Below , evaluated on a selected ordered branch, the expansion of gives . Thus the magnetic-susceptibility critical exponent is on both sides, with different amplitudes. At , the equation of state becomes
so the critical-isotherm exponent is . These are mean-field critical exponents, not a claim that neglecting fluctuations gives the exact Ising transition in every dimension.