Brazovskii model

A Brazovskii model has a quadratic Fourier kernel minimized on a sphere of nonzero wavevector magnitude. The large phase space of soft modes can prevent the Gaussian mass from vanishing and turn a mean-field continuous transition into a fluctuation-induced first-order transition.

A gradient-quartic Brazovskii model stabilizes a negative quadratic gradient coefficient with $\gamma ({\nabla }^2\varphi {)}^2/2$ and uses the quartic interaction $B{\varphi }^2|\nabla \varphi {|}^2$. For $\gamma ,B>0$ and a zero-average compositional order parameter, its nonzero-wavevector instability is a candidate for smectic phase ordering. The Gaussian variational kernel for a gradient quartic interaction shifts both the quadratic coefficients.

For $\varphi =A\cos (q_{0}z)$, the gradient-quartic Brazovskii model has volume-averaged free-energy densityThe averages are $⟨{\cos }^2⟩=⟨{\sin }^2⟩=1/2$ and $⟨{\cos }^2{\sin }^2⟩=1/8$. For $B>0$, the stable amplitude is zero for $a\ge a_c$ and satisfies $A^2=(a_c-a)/(B{q}_0^2)$ below it. The mean-field approximation therefore predicts a continuous phase transition.

For $G(q)=a+\kappa q^2+\gamma q^4$ with $\kappa <0<\gamma$, the minimum occurs on the sphere $q=q_0=\sqrt{-\kappa /(2\gamma )}$. The minimum value is $a-{\kappa }^2/(4\gamma )$.

In three dimensions, let $J(q)=r+\gamma (q^2-q_{\ast }^2{)}^2$, with $q_{\ast }>0$ and small $r>0$. Near the soft shell, $J(q)\simeq r+4\gamma q_{\ast }^2(q-q_{\ast }{)}^2$, soThe radial integral uses ${\int }_{-\infty }^{\infty }ds/(r+A{s}^2)=\pi /\sqrt{Ar}$. The $r^{-1/2}$ divergence obstructs the zero-mass limit of a self-consistent Gaussian variational approximation at a fixed nonzero ordering wavevector. This is the mechanism behind the Brazovskii fluctuation-induced first-order transition; Gross, Ignatiev and Chakraborty's study of fluctuation-driven ordering analyzes the corresponding standard Brazovskii model.

In a self-consistent Gaussian treatment, fluctuations near the soft-mode sphere generate a positive mass shift that diverges as the renormalized mass approaches zero. The disordered phase therefore remains locally stable until its free energy crosses that of a finite-amplitude modulated phase, producing a first-order transition.