Brillouin's theorem

At Hartree-Fock stationarity,

⟨ Φ_{0} ∣ H ∣ Φ_{i}^{a} ⟩ = 0

for each occupied-virtual single excitation.

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Past exam of the chemistry course of the year 3 of the natural sciences course of the University of Cambridge / 2022 / Paper 4 / 60 / b / iii / Solution

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