Fullerene Created 2026-10-31 Updated 2026-11-05
John R. D. Copley Created 2026-10-18 Updated 2026-11-05
A physicist whose neutron scattering research investigated condensed matter, including solid buckminsterfullerene. Neutrons provide structural information that complements a material’s bulk properties. He also developed an exposition of neutron diffraction from powdered samples for students and other nonspecialists, making the connection between measured scattering patterns and material structure more accessible.[ref]
Laytonsville Man Honored for Distinguished Science Writing by NIST. 1999 institutional award account: fullerene studies and neutron-powder-diffraction exposition
Past exam of the chemistry A course of the University of Cambridge 2024 Paper 1 A4 c ii Solution 2026-10-20
The highest expected orbital degeneracy is five. Ideal buckminsterfullerene has Ih molecular point group symmetry. Its irreducible orbital representations include five-dimensional and representations; no single-valued orbital irrep has higher dimension.
This counts distinct spatial molecular orbitals. It does not multiply by electron spin, and it excludes accidental coincidences between unrelated irreps. In a real environment, symmetry lowering can split these degeneracies.[ref]
A zero-dimensional example is buckminsterfullerene, : a closed cage with 60 vertices, 90 edges, 12 pentagons and 20 hexagons. Euler's relation is . Each carbon has three neighbors in a curved, approximately -bonded network; bonds are not all equivalent. Its cage diameter is of order .
Confinement in all directions gives discrete molecular orbitals, unlike the extended dispersion of graphene. It is an electron acceptor with characteristic electronic and vibrational spectra. Its pentagons supply the positive curvature needed to close the carbon network. A molecular solid of cages is held together predominantly by intermolecular forces, so its mechanical and electrical properties differ from those of an individual strongly bonded cage. Undoped fullerene is not a high-conductivity graphene sheet; doping, packing and charge transfer can strongly change transport.