Neutron diffraction

In neutron diffraction, coherent elastic scattering adds scattering amplitudes from regularly positioned scatterers. Since $E_f=E_i$, the neutron scattering kinematics gives $k_f=k_i=2\pi /\lambda$ andFor lattice planes of interplanar spacing $d_{\mathrm{p}}$, constructive addition requires $Q=2\pi n/d_{\mathrm{p}}$ along the plane normal. Equating these expressions proves Bragg's law:For example, stipulate $d_{\mathrm{p}}=2$ ångströms and $\lambda =2$ ångströms. The first diffraction order has $\theta =30^{\circ }$ and detector deflection $60^{\circ }$. A peak position constrains a period; its intensity also depends on the crystal basis structure factor.

Clifford Glenwood Shull describes powdered sodium chloride, a crystal monochromator, and a shielded counter recording angular counts. Inserting cadmium measured background; substantial diffuse scattering complicated peak interpretation.^[ref]

Powdering supplies many crystal orientations. Comparing the angular peaks with Bragg's law constrains crystal structure; a background estimate helps distinguish specimen peaks from unwanted counts. A two-axis diffraction instrument has no separate outgoing energy analysis, so an angular pattern alone does not separate every inelastic contribution. The richer magnetic example, including a warm/cold comparison and its limits, is the manganese monoxide neutron diffraction experiment. Its extra peaks reveal magnetic order beyond the chemical periodicity; the associated magnetic neutron diffraction model is developed there.

The nuclear neutron scattering length is the effective length coefficient for low-energy nuclear scattering amplitude. For the elementary coherent calculation below, use a bound coherent coefficient $b_j$ for each site, and neglect absorption so that $b_j$ is real. This coefficient describes the atomic nucleus, including its isotope and nuclear spin dependence; it is not proportional to atomic number. Replacing nuclear coefficients by electronic magnetic moments would describe a different scattering channel, with additional direction and spatial-distribution factors, as explained in magnetic neutron diffraction.

Choose a one-dimensional crystal with cell translation $a$ and two atoms per cell at $0$ and $d=a/2$. Here $d$ is an intracell displacement, distinct from the interplanar spacing $d_{\mathrm{p}}$ above. In a single-scattering approximation, a row of $N$ cells has scattering amplitudeThe sum selects reciprocal lattice positions $Q_h=2\pi h/a$ as $N$ becomes large. At these positions, the two-site crystal basis structure factor and its squared magnitude areConsequently $b_1=b_2=b$ gives even reflections of strength $4b^2$ and extinguishes the odd reflections. Choosing $b_1=b$, $b_2=b/2$ instead gives $9b^2/4$ and $b^2/4$: the odd/even ratio is $1/9$. Equal atomic numbers would not establish equal $b_j$ if the isotopes differ. The figure below plots these chosen coefficients, without assigning them to actual elements. Missing reflections can encode destructive wave interference within a cell, not the absence of matter at a site.