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Cavity quantum electrodynamics studies chemical atoms interacting with an electromagnetic field confined in a cavity, including regimes where a single photon appreciably affects the dynamics.

In the 2007 cavity quantum electrodynamics experiment of Christine Guerlin and collaborators, including Sébastien Gleyzes, Michel Brune, Jean-Michel Raimond and Serge Haroche, an injected coherent state occupied a 51.1 GHz microwave cavity with niobium-coated mirrors exhibiting superconductivity. Velocity-selected rubidium chemical atoms were prepared as circular Rydberg atoms in levels with principal quantum numbers 50 and 51. Repeated atomic readouts progressively narrowed the inferred photon number to a Fock state; later records revealed jumps. The cavity damping time was $T_c=0.130\mathrm{s}$. Empty-cavity Ramsey interferometry scans fixed the analysis-phase origin; weak injected fields refined the response calibration. Finite fringe contrast required calibrated likelihoods; photon losses could interrupt convergence.^[ref]

The functional sequence is preparation, first Ramsey interferometry zone $R_1$, dispersive cavity $C$, second zone $R_2$, and state-selective detection. The first $\pi /2$ microwave pulse prepares an atomic quantum superposition; dispersive atom-cavity coupling adds a photon number-dependent relative quantum phase while suppressing energy exchange. The second pulse converts that quantum phase into atomic populations; state-selective field ionization reads $e$ or $g$. Successive chemical atoms carry the meter records away while the same field remains available.^[ref]

This arrangement makes quantum nondemolition measurement useful for following a field repeatedly and preparing a Fock state by conditioning. The photon number is inferred from a sequence of physical records; it is not a directly visible label attached to a photon. Each atomic probe makes a weak, partial measurement in quantum mechanics of photon number, and the accumulated records can approach a resolved count. A single binary meter need not identify one among many possible Fock states, as perfect discrimination of pure states requires orthogonality.