Chloroform is trichloromethane, . It is a molecular liquid with three chlorine atoms attached to a tetrahedral carbon center.
Deuterated chloroform, , is widely used as an NMR solvent: replacing most proton signal with deuterium reduces the solvent's proton background and supplies a lock signal. Ordinary chloroform and its deuterated isotopologue therefore have closely related chemistry but different spectroscopic roles.

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