Past exam of the mathematics course of the University of Cambridge 2005 ii Paper 4 34D Solution Created 2026-09-24 Updated 2026-10-14
The classical one-particle partition function, with phase-space cell , isFor the homogeneous trap, rescale . The spatial measure contributes , soHere , as specified; the last integral is .
Using the printed convention , the free energy isThis convention treats the particles as labeled. For indistinguishable classical particles, adds to . It changes the entropy by but leaves the following force, energy and heat capacities unchanged. This normalization qualification is required to distinguish the printed expression from the usual Gibbs-corrected gas free energy.
The generalized force conjugate to the external parameter is , henceIt is the same equation of state as a hard-wall ideal gas, although now dilates a soft confining potential rather than being the occupied geometric volume.
Writing , thermodynamic differentiation givesThe mean kinetic energy is and the trap potential contributes . At fixed , , so . ConsequentlyThe same result follows from enthalpy . These identities describe the classical ideal gas in a homogeneous soft trap.