Collisional phase gate ($U_{\varphi }=\exp (-i\varphi |01⟩⟨01|)$)

A two-qubit gate in which an interaction shifts the energy of a selected joint computational basis state and thereby accumulates a relative quantum phase. With Hamiltonian operator $H=\Omega |01⟩⟨01|$, where $\Omega$ has units of energy, an interaction time $\tau$ gives $U_{\varphi }=\mathrm{diag}(1,e^{-i\varphi },1,1)$ with $\varphi =\Omega \tau /\hslash$. The selected basis state is part of the convention: this gate differs from the usual Controlled-Z gate at $\varphi =\pi$. Conjugation by a Pauli X gate on the first qubit gives $(X\otimes I)U_{\pi }(X\otimes I)=\mathrm{CZ}$, because the conjugation interchanges $|01⟩$ and $|11⟩$.