Complex scalar charge operator ($Q=N_a-N_b$)

For the global phase transformation $\delta \varphi =-i\alpha \varphi$, the Noether current is $j^{\mu }=i({\varphi }^{†}{\partial }^{\mu }\varphi -{\partial }^{\mu }{\varphi }^{†}\varphi )$. The Klein-Gordon equation gives ${\partial }_{\mu }{j}^{\mu }=0$. With zero vacuum charge, its normal-ordered charge is $Q=\int d{\Pi }_p(a^{†}a-b^{†}b)$. Thus $[Q,a^{†}]=a^{†}$, $[Q,b^{†}]=-b^{†}$ and $[Q,\varphi ]=-\varphi$. Particle and antiparticle creation carry opposite charges while both increase energy.

Substituting the free complex scalar field modes into $i\int ({\varphi }^{†}\dot{\varphi }-{\dot{\varphi }}^{†}\varphi )d^{3}x$ gives the formally ordered expression $Q_{\mathrm{bare}}=\int d{\Pi }_p(a^{†}a-b{b}^{†})$. Its divergent vacuum constant is removed by normal ordering, equivalently by choosing $Q|0⟩=0$. The resulting complex scalar charge operator has $[Q,a^{†}]=a^{†}$ and $[Q,b^{†}]=-b^{†}$. Subtracting the constant changes neither its action on fields nor current conservation, but it is essential when identifying the vacuum charge and the charges of one-particle states.