Write the trap angular frequency as and the single-particle oscillator length as . The center of mass coordinate and relative coordinate give independent quantum harmonic oscillators, both of frequency , with masses and reduced mass . Label their excitation numbers by and . The unperturbed energy eigenvalue is .
Particle exchange leaves unchanged and sends to . The exchange symmetry of two identical spin-one-half fermions therefore requires even to accompany the spin-one-half singlet state, and odd to accompany a spin-one-half triplet state. For the contact shifts of two spin-one-half fermions in a harmonic trap, the delta potential depends only on . For odd , the relative wavefunction vanishes at , so its contact shift is zero. Within the first-excited manifold, both perturbations are diagonal in the labels : this is a perturbation diagonal within a degenerate eigenspace. For , the relative oscillator length is , giving the first-order nondegenerate perturbation theory shiftThe Zeeman splitting is for total spin projection . Thus the five lowest states, counted with multiplicity, haveunder the assumed conditions . The three triplet states have slopes , while both singlet states are field independent at this order. The three triplet state branches coincide at zero magnetic field. Their crossing with the excited singlet state is allowed because the total-spin sectors do not mix. The odd relative wavefunctions are in fact unaffected by this delta potential at any coupling; the displayed singlet state shifts retain only first order.
