For gently curved interacting surfaces whose range and closest gap are small compared with their radii, integrate the local planar interaction over nearly parallel surface elements. With the planar interaction free energy per area and , the local gap for two spheres is , where . Thus when . Equal spheres have ; a sphere and plane have . Use consistent surface boundary conditions when supplying the planar interaction.
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The Derjaguin approximation is a concept in colloid and surface science that helps to estimate the interaction forces between spherical particles or between a spherical particle and a flat surface. It is particularly useful in the context of colloidal suspensions and thin films, where understanding the forces acting between particles is essential for predicting their behavior. The Derjaguin approximation states that the interaction force between two spheres can be approximated by considering the force between a flat surface and a sphere.