Well-separated shrinking spheres respond independently at leading order, so their polarization contributions add according to volume fraction. Clusters kept at fixed relative internal separation can have a different leading response; the dilute limit alone does not guarantee independent-sphere polarizability.
Matching the far dipole of a spherical composite with the sum of isolated spherical-inclusion dipoles gives this approximation. Its dilute expansion is . The rational expression is a useful closure, not the exact conductivity of every spherical-inclusion microstructure.
If the first exciting-field correction at inclusion is , its revised polarization is . Averaging weights it by and gives the displayed second-reflection approximation. Further dipole reflections and finite-size multipoles are neglected.
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