Kai Siegbahn Created 2026-10-24 Updated 2026-11-05
Kai Siegbahn developed electron spectroscopy as a quantitative probe of chemical and electronic structure. In X-ray photoelectron spectroscopy, incident X-rays eject electrons whose measured kinetic energies reveal their binding energies after the instrument's reference offset is accounted for. Small changes of a core-level binding energy reflect the atom's chemical environment. Resolving and calibrating these shifts makes the spectrum sensitive to electronic surroundings as well as elemental identity, linking the spectrometer's design with a physical inference.[ref]
Figure 1.
Portrait of Kai Siegbahn
. Jan Collsiöö, original photograph at Uppsala, 21 October 1981; derivative crop by Materialscientist. Nationaal Archief / ANEFO collection. Creative Commons Attribution-Share Alike 3.0 Netherlands., via Wikimedia Commons. Source.