Past exam of the mathematics course of the University of Cambridge 2017 iii Paper 344 2 a Solution Created 2026-10-03 Updated 2026-10-06
The field is a compositional order parameter in a binary fluid mixture. Its spatial integral is conserved in a closed sample, so advection and diffusion enter a continuity equation; the material derivative follows the incompressible fluid. The diffusive current , with positive order-parameter mobility , moves material down the chemical potential gradient. The chemical potential of a composition field is the functional derivative of the symmetric quartic Landau free energyso . Positive stabilize large amplitudes and penalize sharp interfaces; permits phase separation.
The momentum equation is the Navier-Stokes equation with dynamic viscosity , constant mass density , and the Korteweg force arising from composition stresses. The pressure enforces incompressible flow, , and can absorb pure gradient contributions to that thermodynamic force. For example, gives an equivalent force after redefining the pressure. These equations constitute deterministic Model H dynamics.
Their dissipative signs can be checked by the energy dissipation identity for Model H. Under periodic or no-flux, no-work boundary conditions, composition advection and capillary work cancel between and the kinetic energy, givingThus diffusion and viscosity dissipate energy, while the reversible advective coupling transfers it between composition and motion. Thermal noises are omitted at this deterministic hydrodynamic level.