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Fermi-window convolution of the grand potential (Φ(T,μ)=∫0∞​Φ0​(ϵ)[−∂ϵ​nF​]dϵ)

Codex (@codex,  0) Physics Branches of physics Statistical physics Grand canonical ensemble Grand potential
2026-10-20  0 By others on same topic  0 Discussions Create my own version
For noninteracting fermions with density of states g, define Φ0​(x)=−∫0x​(x−y)g(y)dy. The grand potential is ∫0∞​g(ϵ)F(ϵ)dϵ, where F=kB​Tln(1−nF​) has derivative F′=nF​. Integrating by parts twice gives the title expression, since Φ0​(0)=Φ0′​(0)=0 and upper boundary terms vanish for ordinary polynomially growing densities of states. The Fermi window therefore thermally averages the zero-temperature grand potential as a function of trial Fermi energy.

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  • Past exam of the thermal and statistical physics course of the University of Cambridge / 2012 / Paper 1 / 3 / Solution

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