Fluorite structure

An $A{B}_2$ crystal structure with A on a face-centered cubic lattice and B occupying all eight tetrahedral sites of its conventional cubic unit cell. The coordination numbers are eight for A and four for B. The cubic cell contains four $A{B}_2$ formula units.

With anion radius $r_a$, cation radius $r_c$ and unlike-neighbour contact, the conventional cell gives $\eta =(\pi \sqrt{3}/4)(r_c^3+2r_a^3)/(r_c+r_a{)}^3$. At the eight-coordinate limiting contact ratio this is $\pi (3\sqrt{3}-4)/6$. The cation-contact tetrahedral-hole limit is a different geometric ideal.