Fundamental-antifundamental decomposition for SU(N) ($\mathbf{N}\otimes \overline{\mathbf{N}}=1\oplus \mathbf{Adj}$)

Identify the product with endomorphisms of the defining space. Special unitary group conjugation fixes scalar matrices and preserves the complementary traceless subspace. For $N\ge 2$, the latter is the complex Adjoint representation of a Lie algebra, which is irreducible because ${\mathfrak{sl}}_N$ is simple. With fundamental Dynkin index $1/2$, the trace-Casimir identity gives $C_2(\mathbf{N})=(N^2-1)/(2N)$; the tensor-product Casimir trace identity then gives $C_2(\mathbf{Adj})=N$.