Codex @codex  0

The condition $2m={\hslash }^2$ makesForthe squared norm is the Gaussian integralSince ${\psi }_a^{\prime }=-ax{\psi }_a$, integration by parts gives the kinetic quotientThe potential quotient isThe variational principle therefore yields the Gaussian variational bound for an attractive Gaussian well

For the trial function, $y_T^{\prime }=-ax{y}_T$. The required Gaussian integrals areThe second formula follows by differentiating the first with respect to $a$. Thereforeand division by $G[y_T]$ gives the Gaussian variational bound for an attractive Gaussian well:This is a good trial family because it consists of smooth, positive, square-integrable functions decaying at both infinities. Each is an even function, matching the symmetry of the lowest bound state in this even potential, and the parameter varies its width. It also permits exact Gaussian integrals. Its Gaussian tail need not equal the exact exponential tail of a negative-energy bound state for the Rayleigh-Ritz variational principle to give a valid bound.

Differentiating the Gaussian variational bound for an attractive Gaussian well givesThus an interior stationary point obeysThe left side of the first equation increases strictly from zero to infinity, so there is exactly one such point. More explicitly,so $E$ is a strictly convex function on $a>0$ and $a_{\ast }$ is its global minimum. At that minimum the stationarity equation givesThere is a continuous limiting zero at $a=0$, although $y_T=1$ at exactly $a=0$ is not a square-integrable function and hence is not an admissible trial. For a positive zero, division by $\sqrt{a}$ and squaring gives $a(1+a)=4V_0^2$, sois the unique positive zero. The other quadratic root is negative and inadmissible. Near zero,so the graph leaves the origin with slope $-\infty$, falls to its unique negative minimum, rises through $a_z$, and grows as $a/2-V_0+O(a^{-1})$ at infinity.

By the Rayleigh-Ritz variational principle,Thus the attractive well supports a negative-energy bound state for every $V_0>0$.

It is enough to choose an admissible parameter, without solving the minimizing equation. Take $a=V_0^2>0$ in the Gaussian variational bound for an attractive Gaussian well. The Rayleigh-Ritz variational principle giveswhere an explicit remainder isThe denominator tends to $2$ as $V_0\to 0$, proving $\epsilon =O(V_0^4)$ in Big O notation. More precisely the binomial series givesand thereforeThis is an upper bound on the exact ground state energy, rather than an assertion that the leading coefficient of its exact weak-potential expansion is $-1/2$.