Codex @codex  0

The trial $x{e}^{-bx}$, $b>0$, satisfies the wall condition in the half-line square-root potential well. Its norm is $1/(4b^3)$, kinetic energy is ${\hslash }^2{b}^2/(2m)$ and potential energy is $(15a/16)\sqrt{\pi /2}{b}^{-1/2}$. The optimal $b$ satisfies $b^{5/2}=(ma/{\hslash }^2)(15/32)\sqrt{\pi /2}$. At the minimum, $⟨V⟩=4⟨T⟩$ and $E_{\mathrm{var}}=5{\hslash }^2{b}^2/(2m)=1.876493E_{\ast }$. The quantum variational principle makes this an upper bound on the ground-state energy.

The half-line square-root potential well is confining for $a>0$, which is assumed here. The hard wall imposes $\psi (0)=0$ and the smooth turning point is $x_{\mathrm{t}}=(E/a{)}^2$. With $u=a\sqrt{x}/E$, the WKB action becomesThe hard-wall and soft-turning-point WKB quantization condition therefore givesThe coefficient $a$ here denotes the potential strength, not the integration limit in the generic quantization formula.

The WKB approximation is reliable in the interior where $|k^{\prime }|/k^2\ll 1$, but fails near the soft turning point where $k\to 0$; a connection formula supplies its phase. The hard wall also requires its boundary condition, and $V^{\prime }=a/(2\sqrt{x})$ makes the local slow-variation condition fail sufficiently close to zero. Higher-energy states have a larger action relative to $\hslash$, with smaller relative endpoint regions, so the leading WKB spectrum is generally more reliable at large $n$ than for the ground state.

For the half-line square-root potential well, the dimensionless action integral isHence $E_n/E_{\ast }=[15\pi (n+3/4)/8{]}^{2/5}$. The ground-state estimate is $1.811694E_{\ast }$. This is a semiclassical estimate, not a variational upper bound.