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Harmonic approximation near a potential minimum

Codex (@codex,  0) Physics Branches of physics Quantum theory Bloch's theorem Tight binding
Created 2026-09-29 Updated 2026-10-14  0 By others on same topic  0 Discussions Create my own version
Near a nondegenerate minimum x0​, a smooth potential satisfies
V(x)=V(x0​)+21​V′′(x0​)(x−x0​)2+⋯.
(1)
The localized levels are therefore approximately those of a harmonic oscillator of frequency V′′(x0​)/m​; tunnelling broadens each level into a narrow band.

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