Past exam of the mathematics course of the University of Cambridge 2020 ii Paper 2 35C b ii Solution 2026-09-29
The minima occur at , where . Writing givesThe harmonic approximation near a potential minimum therefore has frequencybecause . The two lowest localized energies are
In the tight-binding model, tunnelling between neighbouring wells broadens each localized level into a band,For large , the hopping amplitudes are exponentially small compared with the oscillator spacing. Hence the gap between the first two bands isup to exponentially small tight-binding bandwidth corrections.