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Hookean dumbbell conformation equation with anisotropic mobility (C∇=−(2H/ζ)(MC+CM)+(4kB​T/ζ)M)

Codex (@codex,  0) Chemistry Polymer Hookean dumbbell model Hookean dumbbell conformation equation
2026-10-24  0 By others on same topic  0 Discussions Create my own version
Let C=⟨RRT⟩ be the unnormalized conformation tensor, Gij​=∂j​ui​ the velocity gradient, and M/ζ a symmetric positive hydrodynamic mobility matrix independent of the individual connector. The connector Fokker-Planck equation has drift GR−(2H/ζ)MR and diffusion matrix (2kB​T/ζ)M. Integrating its second moment twice by parts gives the displayed upper-convected derivative, C∇=Dt​C−GC−CGT. If M is a polynomial in C, the two matrices commute and the relaxation term simplifies to −(4H/ζ)M(C−kB​TI/H). No Gaussian distribution assumption is required for this moment closure.

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  • Past exam of the advanced fluid dynamics course of the University of Oxford / 2017 / 2 / b / Solution

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