In an additive regression model, each component can transfer a constant to the regression intercept, so impose empirical mean-zero constraints, or population mean-zero constraints when appropriate. Even after centering, nonzero component perturbations with at every observed point make the additive decomposition nonidentifiable. Extra smoothing penalties may resolve the fitted decomposition, but centering alone does not remove concurvity.
Concurvity is the nonlinear analogue of multicollinearity: a function of one predictor is exactly or approximately expressible as a sum of functions of other predictors. Exact concurvity can make an additive decomposition nonunique; approximate concurvity makes components difficult to estimate stably. A unique fitted sum need not imply unique individual components.

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